Laith H. K. Al-Jibori and Ahmed S. M. Al-Janabi✉
Department of Chemistry, College of Science, Tikrit University, Tikrit, Iraq
Received: Aug 22, 2023/ Revised: Sept 26, 2023/Accepted: Sept 26, 2023
(✉) Corresponding Author: dr.ahmed.chem@tu.edu.iq
Abstract
Five bivalent metal complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with N-(4-(dimethylamino)benzylidene)benzohydrazide (HDmby) ligand with the general formula [M(Dmby)2(H2O)2] {where MII= Co(1), Ni(2) and Cu(3)} and [M(Dmby)2] {where MII= Zn(4), and Cd(5)} have been synthesized and characterized. The prepared complexes were characterized by 1H NMR, IR spectrometry, UV–Vis spectra, Conductivity measurements, magnetic susceptibility. The Co(II), Ni(II) and Cu(II), complexes were found to have octahedral geometry, whereas the Zn(II) and Cd(II) complexes were of tetrahedral geometry. The anti-microbial activity of the synthesized complexes were investigated against three pathogenic bacteria using inhibition zone method and the order of activity of the complexes was determined to be [Zn(Dmby)2] > [Cu(Dmby)2(H2O)2] > [Ni(Dmby)2(H2O)2] > [Co(Dmby)2(H2O)2] > and [Cd(Dmby)2].
Keywords: Benzohydrazide, Bivalent Metal, Complexes, Anti-Bacterial and Anti–Fungi
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How to cite this article
Al-Jibori, L. H. K. and Al-Janabi, A. S. M. (2023). Spectroscopic characterization, and anti-bacterial activity studies of the benzohydrazide derivatives complexes. Microbial Science Archives, Vol. 3(3), 141-146. https://doi.org/10.47587/MSA.2023.3310
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